Sunday, August 6, 2017

allied chemical says we did it first in nj

while growing crystals in an environment of hydrogen sulfide we vented the gas to the atmodphere only to didcover the lsb's rooftop exhaust vent was adjacent to the intake vent.  thar she blows

what can you expect from a company thst fured the akexandrite crystal groeing department only to recall them weeks later and tell them that they were weeks behind schrduke.alexandrite makes for tunable lasers

the australians fidcovered tbat people study chemistry while american eecute themselves safeky and effectively with feantanyl while states use combinstions of substances that are vastly inferior


make america great again fentsnyl, heroin, and morphine for all and morphine otofucing yeast in every microbrewery



Characteristics of Alexandrite Lasers In Q-Switched And Tuned Operations

[-] Author Affiliations
C. L. SamJ. C. WallingH. P. JenssenR. C. MorrisE. W. O'Dell
Allied Chemical Corporation (United States)
Proc. SPIE 0247, Advances in Laser Engineering and Applications, 130 (October 31, 1980); doi:10.1117/12.959391
Text Size: A A A
From Conference Volume 0247

  • Advances in Laser Engineering and Applications
  • Malcolm L. Stitch
  • San Diego | July 29, 1980


abstract


Alexandrite is a laser crystal which is unique in that it is broadly tunable, is four-level, and has a long storage time making Q-switched operation possible. In addition the crystal is surpassed only by ruby in desirable strength and thermal properties of all practical laser crystals. A simple four-level model that describes the laser operation in alexandrite is presented. The terminal laser level in this model is a set of vibrational states well above the ground state. The initial laser level is a level 800 cm-1 above a long-lived storage level and in thermal equilibrium with it. Experimental results of Q-switched operation and tuned long pulse operation are presented, both as a function of temperature. In Q-switched operation, pulsewidths from 70 ns to 300 ns have been measured and laser efficiency increases with temperature. In tuned operation, the increase in gain with temperature is accompanied by a shift of the tuning curve to the red. Both observations are consistent with the simple model. Some laser design parameters are discussed.
© (1980) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.
Citation
C. L. Sam ; J. C. Walling ; H. P. Jenssen ; R. C. Morris and E. W. O'Dell
"Characteristics of Alexandrite Lasers In Q-Switched And Tuned Operations", Proc. SPIE 0247, Advances in Laser Engineering and Applications, 130 (October 31, 1980); doi:10.1117/12.959391; http://dx.doi.org/10.1117/12.959391

Access This Proceeding


Hydrogen sulfide

Chemical compound
Hydrogen sulfide (British Englishhydrogen sulphide) is the chemical compound with the formula H2S, is a colorless, toxic, flammable gas that is responsible for the foul smell of rotten eggs and flatulence. It often results when bacteria break down organic matter in the absence of oxygen. This happens in swamps, and sewers (alongside the process of anaerobic digestion). It also occurs in volcanic gases, natural gas and some well waters. This is the smell that people often think to be that of sulfur. But sulfur itself does not smell.
Hydrogen sulfide
Hydrogen-sulfide-2D-dimensions.svg
Hydrogen-sulfide-3D-vdW.svg
Other namesDihydrogen monosulfide
Dihydrogen sulfide
Sewer gas
Stink damp
Sulfane
Sulfurated hydrogen
Sulfureted hydrogen
Sulfuretted hydrogen
Sulfur hydride
Identifiers
CAS number7783-06-4
PubChem402
EC number231-977-3
KEGGC00283
MeSHHydrogen+sulfide
ChEBICHEBI:16136
RTECS numberMX1225000
SMILESS
Beilstein Reference3535004
Gmelin Reference303
3DMetB01206
Properties
Molecular formulaH2S
Molar mass34.08 g mol-1
AppearanceColorless gas
Odorfaint rotten egg
Density1.363 g dm-3
Melting point
-82 °C, 191 K, -116 °F
Boiling point
-60 °C, 213 K, -76 °F
Solubility in water4 g dm-3 (at 20 °C)
Vapor pressure1740 kPa (at 21 °C)
Acidity (pKa)7.0[2]
Basicity (pKb)6.95
Refractive index (nD)1.000644 (0 °C)[3]
Structure
Molecular shapeBent
Dipole moment0.97 D
Thermochemistry
Std enthalpy of
formation
 Î”fHo298
−21 kJ·mol−1[4]
Standard molar
entropy
 So298
206 J·mol−1·K−1[4]
Specific heat capacityC1.003 J K-1 g-1
Hazards
EU classificationFlammable F+ Very ToxicT+ Dangerous for the Environment (Nature) N
EU Index016-001-00-4
NFPA 704
NFPA 704.svg
4
4
0
R-phrasesR12R26R50
S-phrases(S1/2)S9Template:S16S36Template:S38S45S61
Flash point-82.4 °C.[5]
Autoignition
temperature
232 °C
Explosive limits4.3–46%
Related compounds
Related hydrogen chalcogenidesWater
Hydrogen selenide
Hydrogen telluride
Hydrogen polonide
Hydrogen disulfide
Sulfanyl
Related compoundsPhosphine
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Hydrogen sulfide is also known as sulfanesulfur hydridesour gassulfurated hydrogenhydrosulfuric acidsewer gas and stink dampIUPACaccepts the names "hydrogen sulfide" and "sulfane". When people speak of more complicated compounds they always use the term "sulfane".

Contents

Occurrence

SafetyEdit

Hydrogen sulfide is a highly toxic and flammable gas. Because it is heavier than air it tends to accumulate at the bottom of poorly ventilated spaces.

ToxicityEdit

Hydrogen sulfide is considered a broad-spectrum poison, meaning that it can poison several different systems in the body, although the nervous system is most affected. The toxicity of H2S is comparable with that of hydrogen cyanide.

ReferenceEdit

  1.  "Hydrogen Sulfide - PubChem Public Chemical Database"The PubChem Project. USA: National Center for Biotechnology Informationhttp://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=402&loc=ec_rcs.
  2.  Perrin, D.D., Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution, 2nd Ed., Pergamon Press: Oxford, 1982.
  3.  Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0-07-049439-8
  4. ↑ 4.0 4.1 Zumdahl, Steven S. (2009). Chemical Principles 6th Ed.. Houghton Mifflin Company. p. A23. ISBN 0-618-94690-X.
  5.  Hydrogen sulfide: Overview, National Pollutant Inventory, Australia
  6.  "Southern Natural Gas Company Tariff, General Terms and Conditions Section 3.1(b)"http://ixsnp.sonetpremier.com/ebbmasterpage/Tariff/OrgChart.aspx?code=SNG&pdftag=gtcq. Retrieved October 18, 2011.
  • "Hydrogen Sulfide", Committee on Medical and Biological Effects of Environmental Pollutants, University Park Press, 1979, Baltimore. ISBN 0-8391-0127-9

Other websitesEdit

No comments:

Post a Comment